Electronic Resource

The siamese-twin porphyrin and its copper and nickel complexes: a non-innocent twist

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This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications.

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Ketersediaan

Informasi Detail

Judul Seri

Springer Theses

No. Panggil

E224

Penerbit

Cham : Springer., 2013

Deskripsi Fisik

XVIII, 158 lembar : il. warna

Bahasa

English

ISBN/ISSN

9783319016740

Klasifikasi

NONE

Tipe Isi

text

Tipe Media

computer

Tipe Pembawa

online resource

Edisi

-

Subjek

Kimia Anorganik
Kimia Bio Organik

Info Detail Spesifik

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Pernyataan Tanggungjawab

Lina K. Blusch

Versi lain/terkait

Lampiran Berkas

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